Gas Laws

The simple gas laws describe the relationships between pairs of four basic physical properties: pressure (P), volume (V), temperature (T), and amount in moles (n).

By Sakshi Goel | 28 Oct'18 | 2 K Views |

Theory

Boyle’s Law: Volume and Pressure:

This law illustrates inverse relationship between volume and pressure—an increase in one results in a decrease in the other, keeping temperature and number of moles constant.
V proportional to 1 over P

Boyle’s law follows from the idea that pressure results from the collisions of the gas particles with the walls of their container. If the volume of a gas sample is decreased, the same number of gas particles is crowded into a smaller volume, resulting in more collisions with the walls and therefore an increase in the pressure.
PV = constant
For two different sets of conditions, P1V1 = constant = P2V2
or, P1V1 = P2V2
where and are the initial pressure and volume of the gas and and are the final pressure and volume.


Charles’s Law: Volume and Temperature:

Charles showed that volume and temperature are linearly related, keeping pressure and number of moles constant.
V proportional to T
or V over T equals c o n s tan t


When the temperature of a gas sample is increased, the gas particles move faster; collisions with the walls are more frequent, and the force exerted with each collision is greater.
For two different measurements, 
V subscript 1 over T subscript 1 equals V subscript 2 over T subscript 2
where and are the initial volume and temperature of the gas and and are the final volume and temperature. The temperatures must always be expressed in kelvins (K).


Avogadro’s Law: Volume and Amount (in Moles):

According to this law, there is direct proportionality of volume and number of moles, as long as the pressure and temperature of the gas are constant.
V proportional to n
or V subscript 1 over n subscript 1 equals V subscript 2 over n subscript 2
 where and are the initial volume and number of moles of the gas and and are the final volume and number of moles.

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